Do you know if there is any existing insulation in the walls or ceiling of the bedroom? Since heat rises you first priority when insulating would be the roof of the bedroom, then the walls. Although you will lose heat through the floor if there is little or no insulation, it shouldn't be the biggest factor if the room is cold.
If you did want to start off by insulating the roof of the car port, I would of thought insulation boards (there are a lot of these available, a lot would depend on your budget) would be the easiest solution - a rigid insulation is generally the simplest to fix into place. I don't think there are any regulations to cover this, or at least I'm not familiar with any, but I would guess if there is a large amount of heat being lost through the floor due to the relative heat transfer something like 60mm to 100mm board would make a big improvement.
Sorry if that's a little vague, hope it helps
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